Colloidal processing of Al2O3-doped zirconia ceramics with CaO–P2O5–SiO2 glass as additive

Well-dispersed concentrated aqueous suspensions of Al₂O₃-doped Y-TZP (AY-TZP), AY-TZP with 5.4 vol% of CaO–P₂O₅–SiO₂ (CaPSi) glass (AY-TZP5) and 10.5 vol% CaPSi glass (AY-TZP10), with ammonium polyacrylate (NH₄PA) dispersant were prepared to produce slip cast compacts. The rheological properties of 35 and 40 vol% slips were studied. The densification, microstructure as well as hardness and fracture toughness were investigated as a function of CaPSi glass content at 1300°C-1500°C. The optimum NH₄PA concentration of 35 vol% AY-TZP5 and AY-TZP10 slips at pH ~9 was found to be about 43% and 67% greater than that of AY-TZP slips; this behavior was related to the greater amounts of Ca²⁺ ions leached out from the CaPSi glass surface. The viscosity of stabilized 40 vol% slips with NH₄PA attained a minimum value at 5.4 vol% CaPSi glass addition, and resulted in a more dense packing of cast samples. AY-TZP5 can be sintered at a lower temperature (1300°C) compared to that of AY-TZP. AY-TZP5 exhibited a fine microstructure of tetragonal ZrO₂ (grain sizes below 0.3 µm), and ZrSiO₄–Ca₂P₂O₇ particles homogeneously distributed within the zirconia matrix. It presented similar fracture toughness and a slightly lower hardness compared to those of AY-TZP.     

DP980高强钢连续退火后的组织与性能

研究了不同工艺参数对980 MPa级连续退火双相钢组织及力学性能的影响,利用光学显微镜、透射电镜(TEM)以及拉伸试验对双相钢的微观组织和力学性能进行测试及分析。结果表明:DP980钢的退火组织主要由铁素体、马氏体岛和少量的贝氏体组成,马氏体岛附近的位错密度较高。随着均热温度的升高,DP980钢的抗拉强度呈现先降低后升高的趋势,屈服强度与抗拉强度的趋势一致,伸长率先升高后降低。随着过时效温度的升高,DP980钢的抗拉强度和屈服强度降低,降低幅度较小,伸长率上升,但变化不明显,说明通过调整过时效温度来调控其力学性能的作用较小。     

Room temperature response and enhanced hydrogen sensing in size selected Pd-C core-shell nanoparticles: Role of carbon shell and Pd-C interface

In the present work, the effect of carbon shell around size selected palladium (Pd) nanoparticles on hydrogen (H₂) sensing has been studied by investigating the sensing response of Pd-C core-shell nanoparticles having a fixed core size and different shell thickness. The H₂ sensing response of sensors based on Pd and Pd-C nanoparticles deposited on SiO₂ and graphene substrate has been measured over a temperature range of 25 °C–150 °C. It is observed that Pd-C nanoparticle sensor shows higher sensitivity with increase in shell thickness and faster response/recovery in comparison to that of Pd nanoparticle samples. Pd-C nanoparticles show room temperature H₂ sensitivity in contrast to Pd nanoparticles which respond only at higher temperatures. Role of carbon shell is also understood by investigating H₂ sensing properties of Pd and Pd-C nanoparticles on graphene substrates. These results show that higher catalytic activity and electronic interaction at Pd-C interface, a complete coverage and protection of Pd surface by carbon and presence of structural defects in nanoparticle core are important for room temperature and higher sensing response.     

低能量密度炸药连续装药光面爆破技术研究

为了提高光面爆破成型质量，提出了一种低能量密度炸药连续装药光面爆破技术，利用LS DYNA进行数值模拟，对比2#岩石乳化炸药间隔装药和低能量密度炸药连续装药的应力场，然后将此技术用于长九（神山）灰岩矿四号隧洞控制爆破和露天边坡光面爆破。结果表明：2#岩石乳化炸药间隔装药模型中，装药段与非装药段测点应力峰值相差很大；而在低能量密度炸药连续装药模型中，沿炮孔轴向相同爆心距的测点应力峰值保持一致；使用低能量密度炸药进行连续装药，能够避免装药段的过度破坏和非装药段的欠挖，提高残孔率，且省去了导爆索捆绑时间，提高周边孔装药效率，节省了爆破成本。     

弹性地基处周期性圆形钢筋混凝土管道振动特性分析

针对弹性地基处周期性钢筋混凝土管道的波动特性,基于声子晶体理论和Flugge壳体理论,建立了圆形管道环径向轴对称波动微分方程,利用传递矩阵法建立了相邻胞元间的传递矩阵,数值分析了周期性管道结构的能带特性。结果表明,振动波在传播过程中存在禁带域和通带域,弹性地基对弯曲波在特定频率范围内的传播具有抑制作用,长度比的变化对周期性圆形混凝土管道禁带的幅值、宽度和个数影响显著,因此可通过调整结构尺寸参数改变结构中波的传播特性。     

缓冷出口温度对连续退火SPCC冷轧薄板屈服强度的影响

研究了缓冷出口温度对连续退火SPCC冷轧薄板组织和屈服强度的影响。结果表明:连续退火SPCC冷轧薄板的组织由等轴的铁素体晶粒和晶界处的块状渗碳体及晶粒内的颗粒状渗碳体组成。随着缓冷出口温度从680 ℃提高至700 ℃,平均晶粒尺寸从10.1 μm增加至12.5 μm;此外,提高缓冷出口温度还能够抑制晶界处块状渗碳体的形成,促进晶粒内细小渗碳体更加细小弥散的析出。当缓冷出口温度从680 ℃提高至700 ℃时,冷轧薄板的屈服强度约降低了28 MPa。     

Fabrication of poly(ε‐caprolactone) (PCL)/poly(propylene carbonate) (PPC)/ethylene‐α‐octene block copolymer (OBC) triple shape memory blends with cycling performance by constructing a co‐continuous phase morphology

In this paper, a triple shape memory material was prepared by ultra‐simple melt blending from poly(ε‐caprolactone) (PCL), poly(propylene carbonate) (PPC) and ethylene‐α‐octene block copolymer (OBC). The obtained material possessed a co‐continuous phase morphology and presented an excellent triple shape memory effect (triple‐SME). Theoretical prediction demonstrated that a special continuous phase morphology could be constructed by adjusting the proportions of the blend. Moreover, the results indicated that a close relationship existed between the phase morphology and the triple‐SME of PCL/PPC/OBC. The sample with 35 vol% PPC content contributed to the formation of a continuous phase morphology and exhibited the optimal triple‐SME. Additionally, the sample PCL/PPC/OBC (32.5/35/32.5) showed outstanding structure and performance stability during cycle loading–unloading tests, which evidenced the prominent cycling shape memory property (nearly 100% shape fixing and recovery of temporary shape). Overall, this work could provide an efficient, convenient and recyclable method to obtain high‐performance shape memory materials. © 2020 Society of Chemical Industry     

辊速差对连铸连轧7075铝板显微组织、织构及力学性能的影响

研究辊速差对连铸连轧7075铝板显微组织、织构及力学性能的影响。采用3种不同上辊/下辊转速比(ω/ω0,ω为上辊转速,ω0为下辊转速)1:1、1:1.2及1:1.4进行多次试验。结果显示,在最大辊速差条件下(ω/ω0=1:1.4),7075铝板在轧制方向的屈服强度和极限抗拉强度分别提高41.5%和21.9%。此外,当辊速比ω/ω0为1:1.4时,成品轧制板的平均晶粒尺寸减小36%,横剖面平均硬度增加约9.2%。织构研究结果显示,辊速差越大,成品各向同性及硬度越大。然而,采用不同辊速度的连铸连轧会导致变形板伸长率降低约6%。     

小型核桃脱壳分选一体机的设计

核桃不仅营养价值极高,而且核桃壳的药用价值也非常高,国内小企业和家庭在核桃硬壳脱壳加工环节,一般采用人工破壳取仁的方式,这种方式劳动强度大,人工成本高且不卫生;针对这个问题设计了一款小型的硬壳脱壳,壳仁分离分选的机器来提高生产效率,减少成本,提高收入。